The Synthesis and the Absolute Configuration of Phoracantholide I and J; The Defensive Secretion of the Eucarypt Longicorn, Phoracantha synonyma

Takeshi KitaharaDepartment of Agricultural ChemistryThe University of Tokyo, 1-1-1 Yayoi, Bunkyo-ku, Tokyo, 113, Japan

Koshi KosekiDepartment of Agricultural ChemistryThe University of Tokyo, 1-1-1 Yayoi, Bunkyo-ku, Tokyo, 113, Japan

Kenji MoriDepartment of Agricultural ChemistryThe University of Tokyo, 1-1-1 Yayoi, Bunkyo-ku, Tokyo, 113, Japan

Abstract

Both enantiomers of phoracantholide I and J were synthesized from a chiral starting material obtainable via yeast reduction, and the absolute configurations of the natural materials were determined by GLC studies using a chiral stationary phase.

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The Synthesis and the Absolute Configuration of Phoracantholide I and J; The Defensive Secretion of the Eucarypt Longicorn, Phoracantha synonyma

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The Synthesis and the Absolute Configuration of Phoracantholide I and J; The Defensive Secretion of the Eucarypt Longicorn, Phoracantha synonyma

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