Absolute Configuration of Allosamizoline, an Aminocyclitol Derivative of the Chitinase Inhibitor Allosamidin

Shohei SakudaDepartment of Fermentation Technology, Osaka University, Yamada-oka 2-1, Suita-shi, Osaka565, Japan

Akira IsogaiDepartment of Agricultural Chemistry, The University of Tokyo, Bunkyo-ku, Tokyo113, Japan

Shogo MatsumotoDepartment of Agricultural Chemistry, The University of Tokyo, Bunkyo-ku, Tokyo113, Japan

Akinori SuzukiDepartment of Agricultural Chemistry, The University of Tokyo, Bunkyo-ku, Tokyo113, Japan

Koshi KosekiCentral Research Institute, Japan Tobacco Inc., 6-2 Umegaoka, Midori-ku, Yokohama, Kanagawa227, Japan

Hisashi KodamaCentral Research Institute, Japan Tobacco Inc., 6-2 Umegaoka, Midori-ku, Yokohama, Kanagawa227, Japan

Yasuhiro YamadaDepartment of Fermentation Technology, Osaka University, Yamada-oka 2-1, Suita-shi, Osaka565, Japan

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Abstract

The absolute configuration of allosamizoline (1), a constituent aminocyclitol derivative of allosamidin (2), was elucidated by the exciton chirality method using its 3,4-bis[p-(dimethylamino)benzoyl]-6-trityl derivative (7).

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Absolute Configuration of Allosamizoline, an Aminocyclitol Derivative of the Chitinase Inhibitor Allosamidin

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Absolute Configuration of Allosamizoline, an Aminocyclitol Derivative of the Chitinase Inhibitor Allosamidin

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