Electrophilic Reaction on Plinol C and Syntheses of Functionalized 2-Oxabicyclo[2,2, 1]heptane Derivatives

Katsumi KakinumaDepartment of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo152, Japan

Noriaki YamauchiDepartment of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo152, Japan

Yoshinori FujimotoDepartment of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo152, Japan

Abstract

New functionalized 2-oxabicyclo[2,2,1]heptane derivatives were synthesized for their potential biological activities by way of the intramolecular ether bond formation of plinol C that was obtained from linalool by a thermal ene reaction. The mechanism for the ether-forming reactions is discussed.

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Electrophilic Reaction on Plinol C and Syntheses of Functionalized 2-Oxabicyclo[2,2, 1]heptane Derivatives

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Electrophilic Reaction on Plinol C and Syntheses of Functionalized 2-Oxabicyclo[2,2, 1]heptane Derivatives

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