Cleaning of Stack Gases Containing High Concentrations of Nitrogen Oxides

Abstract

Multistage gas absorption of 1–50% nitric oxide, nitrogen dioxide, and nitrogen tetraoxide from air with water or caustic solutions can produce colorless stack discharges. The rate at which NO is oxidized to No₂ in the gas phase and the solubility rate of No₂ in water or solution are highly concentration dependent so that reductions of stack gas concentrations of nitrogen oxides below approximately 200 ppm appear to be impractical. High efficiency absorption combined with elevated discharge of the cleaned, colorless gases is an acceptable method of air pollution control for many troublesome operations. Experiences in the fields of rocketry and nuclear energy are cited. Engineering modifications of metal pickling operations have been found especially helpful in producing effective control at an acceptable cost.