Areawide Trace Metal Concentrations Measured by Multielement Neutron Activation Analysis

Abstract

A suite of 24 hour high volume air particulate samples, collected June 11–12,1969, at 25 locations in the Northwest Indiana area, has been analyzed by nondestructive neutron activation analysis for 30 trace elements. The use of Ge(Li) gamma-ray spectrometry and computer assisted data reduction, combined with 2-4 replications of each analysis, yielded precise results which allowed a study of the geographical distribution patterns of the elements. Some elements, such as Na, K, Ti, Al, Sm, and Eu, show only minor concentration variations over the area,while others, such as Cu, W, Cr, Zn, Sb, Ga, Br, Ag, Fe, and Ce, show large variations, indicative of important local sources. Similar distribution patterns and high correlation coefficients suggest common sources for several elements. The variations of most heavy elements significantly exceed previously reported variations of total particulate, indicating the latter to be an unsatisfactory guide for elemental distribution, especially near pollution sources. Three representative locations for measurement of elemental abundances in the area are suggested. The influence of meteorological conditions and the potential Lake Michigan pollution hazard are discussed