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Original Articles

The Inhibition of Photochemical Smog I. Inhibition by Phenol, Benzaldehyde, and Aniline

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Pages 357-361 | Published online: 15 Mar 2012
 

Abstract

In urban atmospheres hydrocarbons promote the conversion of NO to NO2 under the influence of sunlight, ultimately giving rise to photochemical smog. The conversion results from a long chain process with HO radicals as the chain carrier. If this chain could be interrupted by suitable radical traps, the formation of photochemical smog would be inhibited. In this paper we report the results of studies using phenol, benzaldehyde, and aniline as inhibitors. Mixtures containing 16 mTorr C3H6, 8 mTorr NO, ∼85 Torr 02, and the addi tives were irradiated at 25°C. The NO2 pressure was monitored photometrically. In the absence of additive, the NO2 pressure first increases with irradiation time reaching a maximum conversion corresponding to 70% of the NO at 1 2 minutes. As the radiation time is lengthened, the NO2 pressure drops. With the additive present, the formation of NO2 is delayed. The time to reach the maximum percent conversion of NO to N02 becomes 20, 22, 31, and 40 minutes respectively, for 13 mTorr C6H5OH, 2 mTorr C6H5CHO, 8 mTorr C6H5CHO, and 4.1 mTorr C6H5NH2 added. The problems and possibilities of adding inhibitors to the atmosphere to control air pollution are discussed.

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