Analysis of Fissure-Filled Emeralds and Rubies by Diffuse Reflectance Fourier Transform Infrared Spectroscopy

ABSTRACT

Although diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) is mainly used for powdered solid samples, it was found to be highly effective for the analysis of certain gemstones. Small amounts of oils and resins used to fill cracks and fissures in substandard (included) emeralds and rubies could be detected. Because of their very low levels, these organic adulterants can be difficult to detect by measurement of the infrared transmittance spectrum. Rubies have a significantly larger “window-of-detection” for organic clarifying agents than do emeralds. In some cases the spectral information was sufficient to identify the oil or polymer resin. Emeralds that were treated over 20 years ago are still easily identified. The position of the emerald or ruby in the sample holder can affect the intensity of C-H and O-H stretching frequencies as well as those brands characteristic to the gemstones.

KEY WORDS::

• Gems
• Adulteration
• Oils
• Resins
• Nondestructive Testing