Comparison of low and High Energy Collision-Induced Decompositions of Selected Methyl Ketones

Donald J. Harvan Laboratory of Environmental Chemistry, National Institute of Environmental Health Sciences, P. O. Box 12233, Research Triangle Park, North Carolina, 27709

Jeffrey A. Nystrom Laboratory of Environmental Chemistry, National Institute of Environmental Health Sciences, P. O. Box 12233, Research Triangle Park, North Carolina, 27709; Laboratories of Chemistry, The University of North Carolina, Chapel Hill, North Carolina, 27514

William L. Grady Laboratories of Chemistry, The University of North Carolina, Chapel Hill, North Carolina, 27514

Robert D. Voyksner Laboratory of Environmental Chemistry, National Institute of Environmental Health Sciences, P. O. Box 12233, Research Triangle Park, North Carolina, 27709; Laboratories of Chemistry, The University of North Carolina, Chapel Hill, North Carolina, 27514

Ronald L. Cerny Laboratories of Chemistry, The University of North Carolina, Chapel Hill, North Carolina, 27514

Maurice M. Bursey Laboratories of Chemistry, The University of North Carolina, Chapel Hill, North Carolina, 27514

M. W. Siegel Extranuclear Laboratories, Inc., P. O. Box 11512, Pittsburgh, Pennsylvania, 152381

Jehuda Yinon Laboratory of Environmental Chemistry, National Institute of Environmental Health Sciences, P. O. Box 12233, Research Triangle Park, North Carolina, 27709; On sabbatical leave from the Weizmann Institute of Science, Rehovot, Israel

J. Ronald Hass Laboratory of Environmental Chemistry, National Institute of Environmental Health Sciences, P. O. Box 12233, Research Triangle Park, North Carolina, 27709

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Abstract

Low energy (0–100 eV acceleration tandem quadrapole technique) and high energy (CID-MIKES technique) collision induced decomposition methods are compared, using selected methyl ketones. The compounds studied were acetone, 2-butanone, cyclopropyl methyl ketone, and 3-methyl-2-pentanone.

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Comparison of low and High Energy Collision-Induced Decompositions of Selected Methyl Ketones

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Comparison of low and High Energy Collision-Induced Decompositions of Selected Methyl Ketones

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