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Original Articles

Investigation of Instrument Parameters for the Application of Peroxyoxalate Cheminescence Detection to Microbore Chromatography

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Pages 1539-1552 | Received 24 Apr 1984, Accepted 06 Jun 1984, Published online: 06 Dec 2006
 

Abstract

Peroxyoxalate chemiluminescence generated by the reaction of an oxalate and hydrogen peroxide in the presence of a fluorophor was evaluated as a detection system for microbore liquid chromatography. The results of studies on instrumental parameters show that the signal is increased with short reaction lines, increasing flow cell volume, and enhanced response through detectors with improved optics.

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