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Electrochemistry

Anomalies In Theories of Liquid Membrane Time Responses to Activity Steps

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Pages 1221-1235 | Received 13 Feb 1989, Accepted 15 Feb 1989, Published online: 23 Oct 2006
 

Abstract

Anomalies in the theory of mass transport-determined liquid membrane ISE response have been identified and corrected where possible. an early model of the response has been corrected in light of recent results. the resultant mass transport equations were shown incapable of describing the experimental root time dependence of the response curves, unless other phenomena (e.g., Donnan failure) simultaneously influenced the potential.

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