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SPECTROMETRY

A Novel Fluorescence Detection Method For Organosilakes

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Pages 419-426 | Received 25 Jul 1988, Accepted 01 Nov 1988, Published online: 23 Oct 2006
 

Abstract

Quinones such as phenanthraquinone and anthraquinone react with organosilanes giving persistent, strongly fluorescent radicals. the reactions are photochemically initiated, rapid, and facile; detection of concentrations of silanes in the 10−7 M range are readily achieved. the starting materials do not fluoresce making the procedure simple, selective and specific.

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