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Original Articles

Two Stabilized Calix[6]Cryptand Stereo Isomers used as Stationary Phases for Capillary Gas Chromatography

Pages 3071-3081 | Published online: 27 Feb 2008
 

ABSTRACT

A couple of stabilized calix[6]cryptand steroisomers were synthesized by capping 1,3,5-trimethoxy-p-tert-butylcalix[6]arene with 1,1,1-tri(tosyloxyethoxyethoxymethyl)-propane and used as stationary phases for capillary gas chromatography. Their chromatographic characteristics and separation mechanism for aromatic positional isomers and polycyclic aromatic hydrocarbons are discussed.

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