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Original Articles

Thermal Decomposition Studies on Ammonium Perchlorate—Polybutadiene Composite Propellant

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Pages 99-104 | Received 21 Dec 1976, Accepted 11 May 1977, Published online: 07 May 2007
 

Abstract

The thermal decomposition of ammonium perchlorate based solid composite propellant using carboxyl terminated polybutadiene as binder has been studied employing thermogravimetry and differential thermal analysis techniques. The thermal decomposition characteristics of the propellant have been found to be quite similar to those of pure ammonium perchlorate with activation energy, 32 Kcal/mole and 60 Kcal/mole respectively in the low and high temperature regions. The effect of the sample size and shape on the thermal decomposition has also been evaluated.

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