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Original Articles

Kinetics; of Hydrogen Oxidation Part 5. Inhibition and Catalysis at Low Pressures

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Pages 97-106 | Received 04 Sep 1979, Published online: 27 Apr 2007
 

Abstract

The switching of inhibition to catalysis at low pressures is analysed. It occurs at a certain concentration of hydrogen bromide, which depends on temperature and pressure. Catalysis is caused by very fine balancing of the processes H + HBr ⇌2H2+ Br. Other elementary processes can cause either inhibition or catalysis depending on the kinetic scheme in which they are involved.

Notes

see Table II

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