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Original Articles

Is Gasification Rate Controlling Step in Polymer Ignition?

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Pages 183-194 | Received 28 Jul 1982, Published online: 29 Mar 2007
 

Abstract

A kinetic study of the polymer ignition processes has been carried out from the ignition delay measurements at different temperatures. The process was found to have a low activation energy, and from a comparison with the results of the kinetic study of the polymer gasification, it is argued that the rate controlling step could be the gasification of the degradation products. A pyrolysis gas chromatographic study of several polymers support the above conclusion.

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