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Original Articles

Tunable Diode Laser Absorption Measurements of Nitric Oxide in Combustion Gases

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Pages 81-99 | Received 18 Jan 1983, Accepted 08 May 1983, Published online: 09 Jun 2010
 

Abstract

Absorption of tunable, infrared, diode laser radiation has been used to measure nitric oxide (NO) in combustion gases. Measurements were made in the post flame gases of an atmospheric pressure flat flame burner doped with calibrated amounts of NO (100-2500 ppm) in order to simulate a range of combustion and exhaust gas conditions. Laser absorption measurements of NO were compared with measurements of NO obtained using probe sampling and chemiluminescent analysis. The laser absorption measurements were corrected for the effect or temperature nonuniformities along the optical path. In fuel lean flames, laser and probe determinations were in good agreement and, in addition, agreed with the amount of NO added to the combustion gases. In fuel rich flames, the laser and probe results also agreed, and indicated some decomposition of the added NO.

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