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Original Articles

Radioisotopic Study of Methanol-to-Soot Conversion in Methanol-Hydrocarbon Diffusion Flames

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Pages 203-209 | Received 26 Mar 1984, Accepted 29 May 1984, Published online: 25 Apr 2007
 

Abstract

Abstract–Diffusion (wick) flames were used to study relative soot production from methanol and hydrocarbons in binary liquid solutions. Methanol-toluene and methanol-benzyl alcohol solutions, prepared with C-14 labeled methanol, were burned. Comparison of sott radioactivity with that of the binary solutions indicated that fuel-to-soot conversion is 35-40 times greater for toluene carbon-benzyl alcohol system. Increasing methanol content in the liquid fuel decreased the rate of total soot generation. No soot was collectable at concentrations above a threshold of 0.94 mole fraction methanol. This threshold was also observed in parallel soot generation studies using a visible-light spectrophone and in measurements of flame luminosity as a function of fuel composition.

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