138
Views
43
CrossRef citations to date
0
Altmetric
Original Articles

Acetaldehyde Oxidation in a JSR and Ignition in Shock Waves: Experimental and Comprehensive Kinetic Modeling

, , , , &
Pages 301-316 | Received 23 Mar 1995, Accepted 16 May 1995, Published online: 03 Apr 2007
 

ABSTRACT

Acetaldehyde oxidation in a jet-stirred reactor has been investigated at high temperature (∼900-1300 K) in the pressure range l-10atm. Molecular species concentration profiles of O0, H2, CO, CO2, CH2O, CH4, C2H2, C2H4, C2H6, C3H6, and CH3HCO were obtained by probe sampling and GC ańalysis. Acetaldehyde ignition in shock waves has been investigated in a wide range of conditions (0.5 ≤ φ ≤,2, 1230-2530 K., 2-5 aim), and ignition delay times have been measured. Acetaldehyde oxidation in these conditions was modeled using a comprehensive kinetic reaction mechanism. The proposed mechanism is able to reproduce experimental data obtained in our high-pressure jet stirred reactor and ignition delays measured in shock tube. The same mechanism has also been validated for the oxidation of CH4,C2H2, C2H4, C2H6, C3H6, C3H8, 1-butene, n-butane, mixtures of CH4 with C2H6 and/or C3H8 in the same conditions.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.