![Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days]({"type":"image" , "src" : "/sda/110819/TOC-Subject-Sample-2021-Physical-Sciences.jpg"})
Abstract
The effect of the ac electric field on piezoelectric properties is investigated in lead zirconate-titanate (PZT) films of various compositions and thicknesses. Non-linear piezoelectric properties of PZT films are compared to those of bulk ceramics. It is shown that non-linearity is strongly suppressed in thin films of the submicron thickness whereas thick films (7-8 μm) demonstrate relatively strong non-linearity comparable to that of “hard” PZT ceramics. Non-linearity in thick films is described by the empirical expression d=dlin[1+(dnlE)α] with α=1.2. Tetragonal films with <111> texture show almost field-independent piezoelectric response due to the reduced contribution of 90° domains. The piezoelectric coefficient obeys logarithmic-type frequency dependence. The frequency dispersion increases with ac-field and can be related to the relaxation of non-180° domains. The results provide direct experimental evidence of the domain wall motion contribution to the piezoelectric properties of PZT films.
