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Section ix: Spectroscopic studies and lattice dynamics

The IR properties of SbSI and SbSI:Cl ferroelectric crystal needles and μ-crystals

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Pages 9-16 | Received 25 Aug 1999, Published online: 26 Oct 2011
 

Abstract

The diffusive-reflectance (30°) IR spectroscopy was used to explore IR-optical properties of needle-like SbSI (antimony sulphoiodide) and SbSI:Cl (chloride modified) crystals and μ-crystals (powders). It turned out to be possible to follow paraelectric-ferroelectric (PE-FE) phase transition influence on IR-spectrum as well as to observe the effect of Cl introduction into SbSI structure. Anisotropy in the water adsorption was also observed for unmodified SbSI.

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