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Section ix: Spectroscopic studies and lattice dynamics

Brillouin scattering study of structural phase transition in thiourea

Pages 157-164 | Received 14 Aug 1999, Published online: 26 Oct 2011
 

Abstract

Thiourea SC(NH2)2 is a typical crystal which has many incommensurate phases. Phase transitions of thiourea have been studied by many workers. Thier temperature dependences of Brillouin scattering spectra have been studied in detail. Following results were obtained (1) frequency shifts Δv of TA-mode(C66) showed a small bend at Ti and a small jump at Tc' (2) Δv of LA-mode (C11) had a small jump at Ti and bends at T8 (modulation wave number δ= 1/8) and Tc Integrated intensities of each spectra exhibited various anomalies.

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