Local and Average Structure of Lead Titanate Based Ceramics

J. Frantti Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama, 226-8503, Japan

S. Ivanov X-Ray Laboratory, Department of Inorganic Materials, Karpov Institute of Physical Chemistry, ul. Vorontsovo pole, 10 Moscow, 103064, Russia

J. Lappalainen Microelectronics and Materials Physics Laboratories, University of Oulu, Linnanmaa, P.O. Box 4500, University of Oulu, FIN-90014, Finland

S. Eriksson Studsvik Neutron Research Laboratory, Uppsala University, Nyköping, S-61182, Sweden

V. Lantto Microelectronics and Materials Physics Laboratories, University of Oulu, Linnanmaa, P.O. Box 4500, University of Oulu, FIN-90014, Finland

S. Nishio Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama, 226-8503, Japan

M. Kakihana Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama, 226-8503, Japan

H. Rundlöf Studsvik Neutron Research Laboratory, Uppsala University, Nyköping, S-61182, Sweden

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The revised lattice dynamics of Pb(Zr x Ti 1 m x )O 3 (PZT) with 0.10 h x h 0.54 ceramics is reported. The phase transition from tetragonal phase to the monoclinic phase is proposed to occur via locally distorted regions. Neutron diffraction data suggests that these local regions transform to the monoclinic phase with decreasing temperature, when x , 0.50.

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