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Original Articles

Mapping Surface Polarization in Thin Films of the Ferroelectric Polymer P(VDF-TrFE)

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Pages 51-54 | Received 01 Aug 2003, Accepted 01 Jan 2004, Published online: 07 Sep 2010
 

Abstract

Pyroelectric Scanning Microscopy (PSM) has been developed to enable mapping of surface polarization in ferroelectric thin films, in particular the copolymer polyvinylidene fluoride triflourorethylene, or P(VDF-TrFE). The Chynoweth method for dynamically measuring pyroelectric current is employed in conjunction with a micropositioning system to construct two-dimensional images of the film polarization. These images have revealed an enhancement of the polarization near the edges of the film below the average coercive field, with the center's polarization increasing thereafter to meet the edge value at saturation.

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