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For the first time a high-temperature cubic phase of the tellurium dioxide from the glassy state has been synthesized. According to X-ray data at Cu Kα—radiation and room temperature the parameters of the elementary cubic cell are: a = 9.716 ± 0.005 Å, Z = 16. Possible space symmetry groups are 
or 
.
We are grateful to E.E. Polyakova and A.S. Baskevich for assistance in experimental works, B.N. Litvin for participation in the discussion of results.
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