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Original Articles

Improvement of Ferroelectric Properties of PZT Ceramics by SBT Addition

, , , &
Pages 22-29 | Received 11 Dec 2012, Accepted 12 Mar 2013, Published online: 09 Dec 2013
 

Abstract

(1−x)PZT-xSBT ceramics were prepared by a solid-state mixed oxide method. Phase characteristics of (1−x)PZT-xSBT ceramics showed a PZT phase and new phase in the compositions with 0.1 ≤ x ≤ 0.3, while a mainly new phase was observed in the composition with x = 0.5. The tetragonality (c/a) of PZT phase decreased with increasing in SBT content up to x = 0.3. SEM micrographs of the sample surface showed equiaxed grains of the PZT phase and irregularly-shaped grains of the new phase in samples with 0.1 ≤ x ≤ 0.3. The 0.5PZT-0.5SBT sample showed mainly irregularly-shaped grains of the new phase. The ferroelectric properties of these samples showed that the addition of small amounts of SBT (x = 0.1) into PZT increased the remanent polarization.

Acknowledgments

This work is financially supported by the Thailand Research Fund (TRF) and the National Research University Project under Thailand's Office of the Higher Education Commission (OHEC) and the Australian Research Council under Grant No. DP0988182. JG acknowledges support from DE120102644. The Faculty of Science and the Graduate School, Chiang Mai University is also acknowledged. ON would like to acknowledge financial support from the TRF through the Royal Golden Jubilee Ph.D. Program.

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