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Section B: CHARACTERIZATION OF SINGLE CRYSTALS

Effect of Li-doping on the Ferroelastic Phase Transitions in KSc(MoO4)2

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Pages 110-116 | Received 02 Sep 2013, Accepted 23 Oct 2013, Published online: 29 Apr 2014
 

Abstract

The effect of K+ substitution by Li+ in the lattice of KSc(MoO4)2 on the phase transitions was investigated. In K1-xLixSc(MoO4)2 crystals with a low lithium concentration (x = 0.05) the occurrence of three structural phase transitions was revealed at T1 = 256.2 K, T2 = 238 K and T3 = 184 K, respectively. As compared with pure KSc(MoO4)2, in the mixed crystal the transition point at T1 is shifted to lower temperature and temperature regions of coexistence of low temperature ferroelastic phases at T2 and T3 are widened.

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