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Original Articles

Thermal, Raman, dielectric and ferroelectric properties of 0.975BaTiO3-0.025Pb(Zn1/3Nb2/3)O3 ceramic

, , , , , , & show all
Pages 69-75 | Received 19 Jun 2016, Accepted 27 Mar 2017, Published online: 01 Aug 2017
 

ABSTRACT

A new low-lead content 0.975BaTiO3-0.025PbZn1/3Nb2/3O3 (0.975BT-0.025PZN) ceramic with a high relative density and good mechanical quality was fabricated by the SPS method. X-ray diffraction measurements showed that the obtained specimen possesses a pure perovskite structure. The composition undergoes a sequence of phase transitions as pure BT. Dielectric studies revealed that the dielectric permittivity decreases at its maximum and the phase transitions shift after PZN-doping of BT. In addition, the dielectric dispersion and polarization increases and decreases, respectively. Possible reasons for the observed properties change are discussed. The results show that the investigated ceramic is a promising low-lead material for electronic applications.

Funding

The present work was supported by NCN project (no. 2012/05/B/ST5/00371).

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