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Ferroelectrics Volume 37, 1981 - Issue 1
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Original Articles

Phase transitions in the Pb (Zn1/3Nb2/3)O3-PbTiO3 system

Jun Kuwata Department of Physical Electronics, Tokyo Institute of Technology Ookayama, Meguro-ku, Tokyo, 152, JAPAN
,
Kenji Uchino Department of Physical Electronics, Tokyo Institute of Technology Ookayama, Meguro-ku, Tokyo, 152, JAPAN
&
Shoichiro Nomura Department of Physical Electronics, Tokyo Institute of Technology Ookayama, Meguro-ku, Tokyo, 152, JAPAN
Pages 579-582 | Published online: 07 Feb 2011
 
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Abstract

Two successive phase transitions, changing the crystal symmetry from rhombohedral to tetragonal, and then to cubic on a heating process, have been investigated in the Pb(Zn1/3Nb2/3)O3-PbTiO3 single crystals with the composition near the morphotropic phase boundary. The existence of the morphotropic phase boundary has been confirmed by measuring the dielectric, piezoelectric and pyroelectric constant. Anomalously large electromechanical and piezoelectric constants are observed on the morphotropic phase boundary.

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