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Section 3: Phases transitions (including incommensurate and ferroelastic)

Critical behaviour of [110]-stressed RbCaF3

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Pages 303-308 | Published online: 10 Feb 2011
 

Abstract

We have investigated the cubic to tetragonal phase transition in RbCaF3 under [110] uniaxial stress by monitoring the EPR lines of the cubic Gd3+ centre which shift proportionaly to the square of the order parameter (the rotational anngle of the CaF6 octahedra Φ) or those of the Gd3+-O2- pair which splits linearly in Φ.

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