This work presents a set of material coefficients for a uniaxially 4x stretched 25 μm thick PVDF film. Calculations of the type d = se, where d and e are piezoelectric coefficients and s is the compliance, are used to compare independent measurements of piezoelectric coefficients. The piezoelectric coefficient e333 is found to be constant to strains over 25%. The non-linearities in the dijk coefficients are due to non-linearities in the elastic moduli that are typical of polymers above their glass transition temperature, i.e. strain rate dependent, viscoelastic, temperature dependent.
Polyvinylidene fluoride (PVDF) elastic, piezoelectric, pyroelectric, and dielectric coefficients and their non-linearities
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