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Ferroelectrics Volume 141, 1993 - Issue 1
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Original Articles

Dielectric and pyroelectric properties of [N(CH3)3H]3Sb2Cl9 in the low temperature region

G. Bator Institute of Chemistry, University of Wroclaw, Wroclaw, Poland
,
R. Jakubas Institute of Chemistry, University of Wroclaw, Wroclaw, Poland
,
L. Sobczyk Institute of Chemistry, University of Wroclaw, Wroclaw, Poland
&
J. Mroaz Institute of Physics, Technical University of Wroclaw, Wroclaw, Poland
Pages 177-187 | Published online: 16 Mar 2011
 
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Low frequency dielectric investigations of disordered trimethylammonium cations are presented and discussed. Ordering process of N(CH3)3H+ cations are described by means of an asymmetry of doubleminimum potential. Pyroelectric experiment on TMACA provided clear evidence of another continuous phase transition at 127 K between two ferroelectric phases connected most probably with a motion of CH3 groups.

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Related Research Data

Ferroelasticity and piezoelectricity of organic–inorganic hybrid materials with a one-dimensional anionic structure: so similar, yet so different
Source: Royal Society of Chemistry (RSC)
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