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Section XIV: Thinfilm ferroelectrics: Experiments and materials

EPR of Mn2+ in Sn2P2Se6 ferroelectric

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Pages 261-266 | Received 31 Oct 1993, Published online: 25 Feb 2011
 

Abstract

The temperature dependence of Mn2+ EPR spectrum in Sn2P2Se6 ferroelectric has been obtained. The magnitude of resonant magnetic field is shown to depend on the crystalline field constants ratio B2 o/B2 2 not on their absolute values, if B2 0 oB2 2 ≥ gβH· The Mn2+ EPR line intensity decreses in temperature range 140⩽ ⩽ T ⩽ 192 K. The temperature of EPR spectrum vanishing (T = 192 K) is closed to the temperature of Sn2P2Se6 phase transition from incommersurate to ferroelectric phase (Tc = 193 K).

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