Systematic X-ray diffraction studies of thermal expansion in CsHSO4, CsDSO4, RbHSO4 and Rb3H(SeO4)2 crystals have been carried out. An analysis of the results showed that the fast protonic conductivity is closely connected with the characteristic features of the structure, symmetry and orientation of hydrogens bonds in the crystals of MeXAO4 (Me = NH4, Rb, Cs; X = D, H; A = S, Se) family.
Ferroelectrics
Volume 167, 1995 - Issue 1
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Crystals with disordered hydrogen-bond networks and superprotonic conductivity. Review
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