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Ferroelectrics Volume 172, 1995 - Issue 1
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Interdisciplinary topics

EPR study of phase transitions in magnesium fluorosilicate and fluorogermanate

R. Hrabański Institute of Physics, Technical University of Czěstochowa, Al. Armii Krajowej 19, P1-42-200, Czěstochowa, Poland
&
A. Kassiba Laboratoire de Spectroscopie du Solide (U.R.A. 807), Universite du Maine Avenue Olivier Messiaen, 72017, Le Mans, Cedex, France
Pages 443-448 | Received 06 Sep 1994, Published online: 25 Feb 2011
 
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Abstract

EPR studies of [Mg(H2O)6,]XF6 (X = Si,Ge) single crystals have been performed using Mn2’ paramagnetic probes. The spin-Hamiltonian parameters have been determined in the low and high temperature phases of both systems and discussed in the light of observed structural changes. The EPR line behaviour in the intermediate phase are analysed in the framework of an incommensurate and order-disorder models.

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