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The Journal of Adhesion Volume 88, 2012 - Issue 9
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Original Articles

On the Evaluation of the Acidity and Basicity Parameters of the Surface Free Energy of Polymers

Irina A. Starostina Kazan State Technological University, Kazan, Republic of Tatarstan, Russia
,
Natalia V. Makhrova Kazan State Technological University, Kazan, Republic of Tatarstan, RussiaCorrespondence[email protected]
,
Oleg V. Stoyanov Kazan State Technological University, Kazan, Republic of Tatarstan, Russia
&
Ilya V. Aristov
Pages 751-765 | Received 05 Jun 2011, Accepted 05 Jan 2012, Published online: 21 Aug 2012
 
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Abstract

Polymeric surfaces of polyvinylchloride and polymethylmethacrylate were found to be unsuitable when considered to be monopolar. The acid-base properties of these polymers were studied by using the Berger method, and their composition was analyzed by IR-spectroscopy and quantum chemical analysis. In order to determine the acidity and basicity parameters of the surface free energy (SFE) of smooth solid surfaces, the three-dimentional graphical method was proposed based on nonlinear Della Volpe modification of the van Oss-Chaudhury-Good equation.

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