Asymmetric Induction in Free Radical Additions of Thiols to Olefins

Masakuni Yoshihara Department of Applied Chemistry Faculty of Science and Engineering, Kinki University, Kowakae, Higashi-Osaka, Japan

Kenji Nozaki Department of Applied Chemistry Faculty of Science and Engineering, Kinki University, Kowakae, Higashi-Osaka, Japan

Hisashi Fujihara Department of Applied Chemistry Faculty of Science and Engineering, Kinki University, Kowakae, Higashi-Osaka, Japan

Toshihisa Maeshima Department of Applied Chemistry Faculty of Science and Engineering, Kinki University, Kowakae, Higashi-Osaka, Japan

Abstract

Asymmetric inductions have been achieved in the free radical additions of (1) l-menthyl mercaptoacetate to such prochiral olefins as crotonic acid, methyl crotonate, and a-methylstyrene (enantiofacedifferentiation), and (2) achiral thiols to g-menthyl and isobornyl crotonates (diastereoface differentiation).

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Asymmetric Induction in Free Radical Additions of Thiols to Olefins

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Asymmetric Induction in Free Radical Additions of Thiols to Olefins

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