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Journal of Macromolecular Science: Part A - Chemistry Volume 27, 1990 - Issue 9-11
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Original Articles

Pyrolysis of Polymer Complexes Leading to Air-Stable Ultrafine Metal Particles Uniformly Dispersedin a Carbon Matrix

Seiichi Miyanaga Department of Macromolecular, Science Faculty of Science, Osaka University, Toyonaka, Osaka, 560, Japan
,
Hajime Yasuda Department of Macromolecular, Science Faculty of Science, Osaka University, Toyonaka, Osaka, 560, Japan
,
Akio Hiwara Department of Macromolecular, Science Faculty of Science, Osaka University, Toyonaka, Osaka, 560, Japan
,
Akira Nakumura Department of Macromolecular, Science Faculty of Science, Osaka University, Toyonaka, Osaka, 560, Japan
&
Hiroshi Sakai Department of Chemistry, Faculty of Science, Hiroshima University, Higashi-Senda, Hiroshima, 730, Japan
Pages 1347-1361 | Published online: 16 Apr 2008
 
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Abstract

New types of air-stable metal-carbon composites which contain ultrafine metal particles (Fe, Co, Ni, Pd, Pt, Rh, Cu, etc.) uniformly dispersed in a carbon matrix were obtained by pyrolysis of a variety of soluble organometallic polymers, macromolecular-metal complexes, and blends of coal pitch with metal complexes at 400-1400°C in N2. Some of their unique physical properties and functions are noted.

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