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Abstract
The damping and mechanical properties of ethylene-vinyl acetate rubber (EVM)/nitrile butadiene rubber (NBR) blends, with BIPB (bis (tert-butyl peroxy isopropyl) benzene) as curing agent, were investigated by DMA. It was proved by mechanical performance, DMA and crosslink density data that a chemical crosslinking reaction occurred between EVM and NBR. A new tan δ peak appeared between 40°C and 60°C in EVM/NBR = 80/20, which we suggest was due to a new molecular chain generated between EVM and NBR. Thus, the effective damping temperature range (EDTR) of EVM/NBR = 80/20 was widened from 31.6°C of EVM and 31.7°C of NBR to 40.7°C. The addition of sulfur, as a curing agent for NBR, greatly raised the height of the damping peak of EVM/NBR blend, but only slightly widened the EDTR at a cost of deterioration of mechanical performance. Zinc diacrylate (Zn (Ac)2), as a possible graft addition to the blends, enlarged the damping peak of EVM/NBR, especially widening the EDTR of EVM/NBR = 80/20 to 50.9°C, but with a decline of mechanical properties. PVC was partially miscible with EVM/NBR blends and dramatically widened the EVM/NBR = 80/20 EDTR to 62.4°C.
Acknowledgements
This work was supported by Shandong Provincial Natural Science Foundation (ZR2010EL019).