Higher-Order Structure of Poly(Ethylene 2,6-Naphthalene Dicarboxylate) Fibers Produced by Direct High-Speed Spin-Drawing

Abstract

In order to efficiently produce poly(ethylene naphthalene-2,6-dicarboxylate) (PEN) fibers comprising α-phase crystallites with a high melting temperature, a direct high-speed spin-drawing (HSSD) system was implemented. The higher-order structure of the HSSD PEN fibers was investigated by focusing on the radial anisotropy of the fibers. A nucleating agent was added to the PEN fibers, and its effect on the formation of the higher-order structure was also studied. Highly crystalline PEN fibers predominantly composed of α-phase crystallites were produced by operating the HSSD system at 4 km/min. The PEN fibers exhibited a melting temperature of 288.8 °C and a storage modulus of 31.4 GPa. The excellent thermal stability of the HSSD PEN fibers was presumably brought about by the formation of a shish-kebab-like structure. The generation of the shish-kebab-like structure and radial anisotropy seemed to be more dependent on the effect of tensile stress during the drawing process rather than from the nucleating additive. The nucleating agent used in this study effectively increased both the α- and β-phase crystallite sizes. Such structural modification, however, did not appear to contribute to the thermal stability enhancement of the PEN fibers.

Keywords:

• High-speed spin-drawing
• poly(ethylene naphthalene-2,6-dicarboxylate)
• PEN
• radial anisotropy
• shish-kebab-like structure
• thermal stability

Acknowledgment

The author wishes to thank Mr. Yudai Takahashi, our graduate school student, for his patient work on alkaline etching treatments and DMA measurements.