Recovery of neutron-irradiation-induced defects of Al₂O₃, Y₂O₃, and yttrium-aluminum garnet

ABSTRACT

SiC fiber-reinforced SiC matrix composites (SiC_f/SiC) are considered as one of the candidates for blanket materials in future fusion reactors and as an advanced fuel cladding material for next-generation fission reactors. Generally, the densification of SiC needs sintering additives and oxides such as Al₂O₃, Y₂O₃, and yttrium-aluminum garnet (YAG, Y₃Al₅O₁₂), which are frequently added to SiC. However, the effects of neutron irradiation on sintering additives are still unclear. In this study, we performed the neutron irradiation of Al₂O₃, Y₂O₃, and YAG at fluences up to 2.0–2.5 × 10²⁴ n/m² (E > 0.1 MeV) at 60–90 °C. The isochronal recovery of the macroscopic volume of Al₂O₃ against annealing temperature showed smooth and continuous shrinkage at a temperature of up to 1200 °C, and the volume slightly increased above that temperature. In contrast, the volume of Y₂O₃ showed quick shrinkage at the low temperature range, and slower and smooth recovery was observed up to ∼1100 °C. In the case of YAG, the recovery of volume occurred in a step-wise manner at 600–750 °C, and continuous shrinkage occurred at temperatures lower and higher than that temperature range. The activation energies for the macroscopic volume recoveries of three oxides were obtained from the Arrhenius plots of the rate coefficients. Two-stage recovery was observed for Al₂O₃, whereas more complicated recovery processes were suggested for Y₂O₃ and YAG.

KEYWORDS:

• Al₂O₃, Y₂O₃
• yttrium-aluminum garnet (YAG)
• neutron irradiation
• defect recovery
• activation energy

Acknowledgments

The study was partly supported by a Grant-in-Aid for Scientific Research from the Japan Society for Promotion of Science (Grant Number :23360424) and by the Japan Atomic Energy Agency through ITER-BA activity. The irradiation experiments were performed with support from the staff of the International Research Center for Nuclear Materials Science, Institute for Materials Research, Tohoku University.

Disclosure statement

No potential conflict of interest was reported by the authors.