7
Views
16
CrossRef citations to date
0
Altmetric
Original Articles

The Third Fishenden Memorial Lecture: The Photo-Resist Story—From NiéPce to the Modern Polymer ChemistFootnote

Pages 181-190 | Received 22 May 1964, Published online: 23 Jul 2016
 

Abstract

The photo-resist was first used to provide eorly photographs, then became restricted to photomechanical applications, but recently has found widespread industrial uses. The first system was that of Niepce employing bitumen, but the dichromate methods soon took over. The practical drawbacks of the dichromate system urged more searching for improved methods employing new colloid binders and alternative light-sensitive agents, as well as two-layer systems. Diazo compounds have been shown to photo-crosslink in a similar manner to dichromate and the advent of diazo-resin condensates was important. Needs for a hydrophobic resist system caused much study of methods of sensitizing partially crosslin ed resins in solvent based systems. Poor stability of the systems prevailed, but a break-through occurred with polymers having inherent light sensitivity. The polyvinyl cinnamate system is outstandingly successful and other methods in which hydrophobic resins are sensitized with azides are also of interest. Photo-polymerization of monomer systems has been widely explored and certain processes have been developed. Reversed or direct positive systems are of interest and have received attention including several diazo methods. The ideal resist still remains to be found and the widening applications call for a variety of requirements in the product.

Notes

At present with International Publishing Corporation Ltd, Paper read to the Society on 3 December 1963.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.