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Article

High Pressure Studies on Mesomorphic and Polymesomorphic Transitions

Pages 71-81 | Received 14 Mar 1977, Published online: 28 Mar 2007
 

Abstract

The paper presents the following results: (1) pressure induced mesomorphism in p-p'-n-butylazobenzene and biphenyl p-ethyl benzoate. (2) the monotropic nematic-isotropic transition in trans-p-n-propoxy-x-methyl cyanophenyl cinnamate becoming enantiotropic under pressure, (3) suppression of the cholesteric mesophase in cholesteryl nonanoate and the location of a solid-cholesteric-isotropic triple point at ∼ 2.85 kbar. confirming an earlier observation of Keyes. Weston and Daniels on the same compound, (4) a measurement of dT/dp for the solid-smectic A, smectic A-cholesteric and cholesteric-isotropic transitions in cholesteryl myristate and a comparison with the values evaluated from the Clausius-Clapeyron equation using the known latent heat and volumetric data.

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