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Molecular Crystals and Liquid Crystals Volume 52, 1979 - Issue 1
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Original Articles

An Introduction to the Solid State Polymerization of Transition-metal Complexes: A Comparative Study

K. Cheng Department of Chemistry, Brandeis University, Waltham, Massachusetts, 02154, U.S.A
,
B. M. Foxman Department of Chemistry, Brandeis University, Waltham, Massachusetts, 02154, U.S.A
&
S. W. Gersten Department of Chemistry, Brandeis University, Waltham, Massachusetts, 02154, U.S.A
Pages 77-81 | Received 19 Jul 1978, Published online: 12 Oct 2011
 
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Abstract

Preliminary studies in this laboratory' of topochemical and topotactic polyreactions of NiBr2[P(CH2CH2CN)3]2 have shown that the reactions are in many cases characterized by a) product specificity, b) stereospecificity, c) “crystallographic specificity” and d) highly anisotropic “front motion” through individual single crystals. The polymerization reaction under investigation here is

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