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Original Articles

The Mechanism of Solid-state Polymerizations

Pages 231-233 | Received 16 Jun 1978, Published online: 12 Oct 2011
 

Abstract

A solid-state polymerization can be treated as a special case of a phase change which may proceed homogeneously or heterogeneously. If solid-state chemistry is understood in its broadest sense, also such reactions may be considered which occur at the interphase between a gaseous educt and the crystalline product where e.g. each step of crystal growth occurs with formation of a chemical bond. In polymer science such reactions are called simultaneous polymerization and crystallization.

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