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Articles

Thermoanalytical Microscopy of Phase Transitions of Cholesteryl Acetate-Cholesteryl Octanoate Binary System

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Pages 29-41 | Received 29 Mar 1978, Published online: 28 Mar 2007
 

Abstract

Cholesteryl acetate-cholesteryl octanoate binary system shows an eutectic point and the eutectic has an enantiotropic cholesteric phase, while both components are monotropic. The phase diagram is discussed with the Schröder-van Laar equation.

The cholesteric flow on cooling behaves as a colloidal state, of which selective light scattering appears periodically.

The once melted solid state is modified to be apparently miscible also in the solid state.

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