Enforced Segregated Stacking in Metallomacrocyclic “METALS.” New Information on Phthalocyanine Donor-Acceptor Interactions

Tamotsu Inabe Department of Chemistry and the Materials Research Center, Northwestern University, Evanston, Illinois, 60201

Carl R. Kannewurf Department of Electrical Engineering and Computer Science, and Materials Research Center, Northwestern University, Evanston, Illinois, 60201

Joseph W. Lyding Department of Electrical Engineering and Computer Science, and Materials Research Center, Northwestern University, Evanston, Illinois, 60201

Michael K. Moguel Department of Chemistry and the Materials Research Center, Northwestern University, Evanston, Illinois, 60201

Tobin J. Marks Department of Chemistry and the Materials Research Center, Northwestern University, Evanston, Illinois, 60201

Abstract

The chemical, structural, optical and electrical conductivity characteristics of the cofacially joined metallophthalocyanine polymer [Si(Pc)O]_n are probed in response to incremental doping by organic (dichlorodicyanoquinone) and inorganic (NO⁺BF₄ ⁻, NO⁺PF₆ ⁻) oxidants of greatly differing structural and electronic characteristics. The achievable degree of partial oxidation, the homogeneity of the doping process, and the macroscopic mechanism of charge transport appear to be remarkably similar.

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Enforced Segregated Stacking in Metallomacrocyclic “METALS.” New Information on Phthalocyanine Donor-Acceptor Interactions

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Enforced Segregated Stacking in Metallomacrocyclic “METALS.” New Information on Phthalocyanine Donor-Acceptor Interactions

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