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Liquid Crystals

Study on Molecular Polarizabilities of Cyclohexane Derivatives

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Pages 53-64 | Received 18 Dec 1984, Accepted 11 Jul 1985, Published online: 20 Apr 2011
 

Abstract

The refractive indices and densities have been measured as a function of temperature for trans-4-alkylcyclohexyl 4′-n-pentyloxyphenylester and trans-4-alkylcyclohexyl 4′-cyanophenylester in the liquid crystalline and liquid phases. The molecular polarizabilities have been evaluated by Vuks’ formula. The polarizabilities obtained are compared with those estimated from bond polarizability calculations for the molecules. The relative nematic stabilities of the cyclohexane derivatives are discussed in terms of the molecular parameters measured.

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