Experimental and Theoretical Study of Organic Solid State : Structure and Reactivity

Roger Lamartine Laboratoire de Chimie Industrielle, Villeurbanne, C.N.R.S. U.A. 805 Université Claude Bernard, LYON 1 43 Bd du 11 Novembre 1918, 69622, FRANCE

Claude Decoret Laboratoire de Chimie Industrielle, Villeurbanne, C.N.R.S. U.A. 805 Université Claude Bernard, LYON 1 43 Bd du 11 Novembre 1918, 69622, FRANCE

Jean Royer Laboratoire de Chimie Industrielle, Villeurbanne, C.N.R.S. U.A. 805 Université Claude Bernard, LYON 1 43 Bd du 11 Novembre 1918, 69622, FRANCE

Jacques Vicens Laboratoire de Chimie Industrielle, Villeurbanne, C.N.R.S. U.A. 805 Université Claude Bernard, LYON 1 43 Bd du 11 Novembre 1918, 69622, FRANCE

Abstract

Three of our recent attempts to study the mechanism of organic reactions in the solid phase are presented. The stability of organic crystals of monotropic polymorphic substances is studied. Also described are the rearrangement of orthocyclohexadienone into paracyclohexadienone and the solid state hydrolysis of acetylanthranyl. In all cases it is shown that organic single crystals are useful for the study of reaction mechanisms.

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Experimental and Theoretical Study of Organic Solid State : Structure and Reactivity

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