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Low Dimensional Solids and Molecular Crystals

Effect of Temperature on the Mechanoluminescence of Fluorescent and Phosphorescent Molecular Crystals

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Pages 157-172 | Received 17 Oct 1985, Accepted 20 Aug 1986, Published online: 28 Mar 2007
 

Abstract

The present paper reports the effect of temperature on the mechanoluminescence (ML) intensity of certain fluorescent and phosphorescent molecular crystals. The ML intensity decreases with temperature and follows the relation IT = IO T (1 - T/Tc ) n. The value of n lies between 0.90 and 1.10 for the piezoelectric crystals. Generally the ML of piezoelectric crystals ceases near their melting point, however, it disappears in non-piezoelectric crystals much below their melting points. It is shown that the decrease of ML efficiency with temperature should involve both, the change in crystal properties with temperature and the usual decrease in quantum yield caused by increased radiationless transition.

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