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Liquid Crystals

Order of Polyoxyethylene Chains in the Lamellar Phase of a Nonionic Surfactant

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Pages 55-60 | Received 03 Apr 1987, Published online: 19 Dec 2006
 

Abstract

Lamellar samples of aqueous tetraethylene glycol n-dodecyl ether in varying degrees of selective deuteration were studied by 2H NMR spectroscopy. Order parameter profiles for both the alkyl and oxyethylene head group chain have been obtained. A maximum in the order of the surfactant molecules was found to occur 3-4 methylene segments from the alkyl/headgroup interface on the alkyl chain. Order decreased rapidly with position on either side of this region giving an approximately symmetrical profile.

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